Flow and Diffusion Characteristics of CO2 in Industrial Flue Gas Applied Directly to Gas Fertilizer
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摘要:
工业烟气中的CO2浓度较低,并且含有不同污染物,能否直接用作增施气肥存在一定的不确定性。为研究将工业烟气中CO2直接用于农业生产中增施气肥的可行性,对工业烟气排放后的烟气特性、CO2组成、污染特性进行了分析和评估。基于CFD数值模拟技术,对工业烟气在大棚内的CO2扩散特性进行了模拟分析。研究结果表明,工业烟气中含有不同的污染物成分可能会对大棚内的环境空气质量产生影响,需经过合理评估并采取适当措施后方可满足农业生产的要求。基于燃煤电厂排放的烟气特点,在CO2吸收速率为5×10−8 m3/s、烟气稀释倍数为100,控制进入大棚内的SO2、NO2、Hg、HF和PM等污染物浓度达到15 mg/m3、8 mg/m3、5 μg/m3、0.2 mg/m3和7.5 mg/m3时,可实现大棚内的污染物浓度达到环境空气质量标准的一级标准(GB 3095—2012),并且CO2浓度满足植物生长的浓度要求。不同入口布置方式对大棚内的CO2浓度影响较大,采用两边和中间同时布点的方案可以较好实现CO2浓度在大棚内的均匀性要求。因此,工业烟气中的CO2直接用于农业生产具有可行性,但在实际应用中,应结合烟气中的CO2浓度、植物的吸收速率、CO2喷入位置、稀释倍数和污染物浓度进行综合评估,并应用于农业生产。
Abstract:CO2 concentration in industrial flue gas is low and contains different pollutants, so it is uncertain whether it can be directly used as gas fertilizer.In order to study feasibility of directly using CO2 form industrial flue gas for gas fertilizer agriculture, flue gas characteristics, CO2 composition and its pollutants on agricultural production were analyzed.Based on CFD numerical simulation technology, diffusion and distribution characteristics of CO2 were simulated and analyzed.Results showed that high concentration of CO2 from power, steel, cement or other industrial flue gases could be used for promoting plant growth.Different pollutant components in industrial flue gas may affect ambient air quality in greenhouses, so it only can be used for carbon-rich agriculture after reasonable evaluation or suitable measures were taken.Based on characteristics of flue gas emitted from coal-fired power plants, when CO2 absorption rate was 5×10−8 m3/s and flue gas was diluted by 100 times, moreover, control inlet concentration of SO2, NO2, Hg, HF, PM to 15 mg/m3, 8 mg/m3, 5 μg /m3, 0.2 mg/m3 and 7.5 mg/m3, environmental air quality could be controlled to meet A-level standard of GB 3095—2012.At this point, concentration of CO2 also met concentration requirements of plant growth.Different CO2 inlet has a great influence on CO2 concentration in greenhouse, and scheme of placing points on both sides and in the middle at the same time could get a uniformity requirement of CO2 concentration in greenhouse.Results also showed that directly using from industrial flue gas to carbon-rich agriculture was feasible, but in practical application process, CO2 concentration in flue gas, absorption rate, CO2 injection location, dilution ratio and pollutant concentration must be comprehensively evaluated before applied to agricultural production.
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表 1 工业典型行业烟气中CO2含量
Table 1. CO2 content in flue gas of typical industrial industries
表 2 工业典型工段烟气污染物排放限值对比
Table 2. Comparison of emission limits of flue gas pollutants in typical industrial sections
名称 单位 燃煤电厂
烟气钢铁烧结
烟气电解铝
烟气水泥窑炉
烟气[9]SO2 mg/m3 35* 35* 35* 100 NOx mg/m3 50* 50* / 320 粉尘 mg/m3 10* 10* 10 20 汞及其化合物 mg/m3 0.03 / / 0.05 氟化物 mg/m3 4.0 3.0 3.0 二噁英 ngTEQ/m3 / 0.5 0.5 / 其他 mg/m3 / / 氯化氢30 氨8 注:*为超低排放要求下的排放限值。 表 3 模型边界条件
Table 3. Model boundary conditions
烟气成分 初始含量 入口质量流量/(kg·s−1) 0.0052 CO2体积含量/% 12 O2体积含量/% 6 H2O体积含量/% 15 SO2体积含量/×10−6 12.25 NO2体积含量/×10−6 25.45 HF体积含量/×10−6 0.35 Hg体积含量/×10−12 0.28 -
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