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秸秆基生物炭对设施菜地土壤重金属钝化的时效特征及作用机理

Ageing characteristics and mechanism of straw-based biochar in heavy metal passivation for vegetable facilities soil

  • 摘要: 以玉米秸秆为原料,选取0~20 cm表层设施菜地土壤为供试土壤,设置秸秆基生物炭(MBC)施用量(0%、1%、2%、4%)4个处理组,在25 °C恒温条件下培养180 d,分别于培养1、30、60、90和180 d取样,测定重金属形态、土壤理化性质、MBC吸附量及稳定性,采用SPSS26.0进行单因素方差分析检验差异显著性。结果表明,MBC钝化具有剂量与时效效应,4%处理60 d镉钝化效率达66.67%,180 d仍维持64.15%;4%处理180 d铅钝化效率30.19%,4%处理180 d锌钝化效率28.50%;4%处理180 d 阳离子交换量、有机质含量较CK处理分别提升53.14%、35.18%,MBC通过吸附络合与化学沉淀协同作用钝化重金属,并且稳定性较强。秸秆基生物炭对设施菜地土壤重金属具有长期稳定的钝化效果,可提升土壤肥力。

     

    Abstract: Using corn stover as raw material, 0~20 cm surface from vegetable facilities soil was selected as test soil, with four treatments based on MBC application rates(0%, 1%, 2%, and 4%).Cultivation was conducted at a constant temperature of 25 °C for 180 days.Samples were collected at 1, 30, 60, 90, and 180 days.Heavy metal speciation, soil physicochemical properties, MBC adsorption capacity, and stability were measured.Differences were analyzed by one-way analysis of variance(ANOVA)with SPSS 26.0.Results has indicated that MBC passivation exhibited dose-dependent and time-dependent effect.Treatment with 4% MBC at 60 days achieved cadmium passivation efficiency of 66.67%, which remained at 64.15% after 180 days.Treatment with 4% MBC at 180 days achieved 30.19% lead passivation efficiency, while 4% treatment yielded 28.50% zinc passivation efficiency.Treatment with 4% MBC at 180 days increased CEC and SOM by 53.14% and 35.18% compared to CK, respectively.MBC has passivated heavy metals through synergistic adsorption complexation and chemical precipitation, with strong stability.Straw-based biochar has shown long-term stable passivation effects on heavy metals in vegetable facilities soil while simultaneously increasing soil fertility.

     

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